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一、个人基本资料
姓名:饶华商
性别:男
出生年月:1989年7月
籍贯:江西
二、联系方式
邮箱:raohsh@scau.edu.cn
通讯地址:华南农业大学材料与能源学院
邮编:510642
三、个人简述
饶华商,博士,硕士生导师。2017年在中山大学获得工学博士学位,目前主要从事新型(钙钛矿/量子点)太阳电池相关的材料开发与器件研制工作。2019年,荣获广东省自然科学一等奖(7/9);近年来,在Adv. Mater.、Adv. Funct. Mater.、Nano Energy等国际著名期刊上发表60余篇论文,其中有8篇论文入选“ESI高被引论文”,论文总引用4000余次;申请、授权10项发明专利;参与《染料敏化太阳能电池——从理论基础到技术应用》一书的编撰工作。主持国家自然科学基金面上项目、青年基金项目各一项、华南农业大学青年科技人才培育专项基金一项,并参与多项国家与地方自然科学基金项目;获广州市科协青年人才托举工程项目资助。主要承担《无机及分析化学》《太阳能工程》理论课与实验课的教学工作,在2018年度材料与能源学院第三届青年教师教学观摩竞赛中获得第一名。
四、教育背景
2012.08-2017.06 工学博士 中山大学 材料物理与化学
2008.09-2012.06 理学学士 中山大学 化学
五、工作经历
2017.07-2021.01 华南农业大学,材料与能源学院,首聘副教授
2021.01-至今 华南农业大学,材料与能源学院,副教授
六、科研方向
钙钛矿太阳电池
无机钙钛矿
无机纳米材料设计与制备
七、期刊论文(一作/通迅)
2023年
[1] Liao, Y.; Zhang, J.; Wang, W.; Yang, Z.; Huang, R.; Lin, J.; Che, L.; Yang, G.; Pan, Z.; Rao, H.; Zhong, X., Anti-Dissociation Passivation via Bidentate Anchoring for Efficient Carbon-Based CsPbI2.6Br0.4 Solar Cells. Adv. Funct. Mater. 2023, 2214784.
[2] Zhang, J.; Zhang, G.; Liao, Y.; Pan, Z.; Rao, H.; Zhong, X., Interfacial energy-level alignment via poly-3-hexylthiophene-CsPbI3 quantum dots hybrid hole conductor for efficient carbon-based CsPbI2Br solar cells. Chem. Eng. J. 2023,453, 139842.
[3] Zhang, G.; Zhang, J.; Pan, Z.; Rao, H.; Zhong, X., Enhancing hole extraction via carbon nanotubes/poly(3-hexylthiophene) composite for carbon-based CsPbI2Br solar cells with a new record efficiency. Sci. China Mater. 2023, doi: 10.1007/s40843-022-2343-7.
2022年
[4] Zhang, G.; Zhang, J.; Yang, Z.; Pan, Z.; Rao, H.; Zhong, X., Role of Moisture and Oxygen in Defect Management and Orderly Oxidation Boosting Carbon-Based CsPbI2Br Solar Cells to A New Record Efficiency. Adv. Mater. 2022,34 (40), 2206222.
[5] Zhang, G.; Zhang, J.; Liao, Y.; Pan, Z.; Rao, H.; Zhong, X., Cs2SnI6 nanocrystals enhancing hole extraction for efficient carbon-based CsPbI2Br perovskite solar cells. Chem. Eng. J. 2022,440, 135710.
[6] Yang, Z.; Zhang, G.; Zhang, J.; Pan, Z.; Yang, S.; Liu, B.; Rao, H.; Zhong, X., Synergistic passivation by alkali metal and halogenoid ions for high efficiency HTM-free carbon-based CsPbI2Br solar cells. Chem. Eng. J. 2022,430, 133083.
[7] Xu, S.; Kang, C.; Huang, Z.; Zhang, Z.; Rao, H.; Pan, Z.; Zhong, X., Dual Functional Quantum Dot Seeding Growth of High-Quality Air-Processed CsPbI2Br Film for Carbon-Based Perovskite Solar Cells. Solar RRL 2022,6 (1), 2100989.
[8] Qi, C.; Pan, Z.; Rao, H.; Zhong, X., Free-standing 3D nitrogen-doped graphene/Co4N aerogels with ultrahigh sulfur loading for high volumetric energy density Li-S batteries. J. Alloy. Compd. 2022,901, 163625.
2021年
[9] Zhang, G.; Xie, P.; Huang, Z.; Yang, Z.; Pan, Z.; Fang, Y.; Rao, H.; Zhong, X., Modification of Energy Level Alignment for Boosting Carbon-Based CsPbI2Br Solar Cells with 14% Certified Efficiency. Adv. Funct. Mater. 2021,31 (19), 2011187.
[10] Wang, W.; Lin, Y.; Zhang, G.; Kang, C.; Pan, Z.; Zhong, X.; Rao, H., Modification of compact TiO2 layer by TiCl4-TiCl3 mixture treatment and construction of high-efficiency carbon-based CsPbI2Br perovskite solar cells. J. Energy Chem. 2021,63, 442.
[11] Qi, C.; Zhouhong, Y.; Pan, Z.; Zhong, X.; Rao, H., Lightweight Free-Standing 3D Nitrogen-Doped Graphene/TiN Aerogels with Ultrahigh Sulfur Loading for High Energy Density Li–S Batteries. ACS Appl. Energy Mater. 2021,4 (8), 7599.
2018-2020年
[12] Rao, H.; Zhou, M.; Pan, Z.; Zhong, X., Quantum dot materials engineering boosting the quantum dot sensitized solar cell efficiency over 13%. J. Mater. Chem. A 2020,8 (20), 10233.
[13] Song, H.; Rao, H.; Zhong, X., Recent advances of electrolyte in quantum dot-sensitized solar cells. J. Mater. Chem. A 2018,6 (12), 4895.
[14] Huang, D.; Xie, P.; Pan, Z.; Rao, H.; Zhong, X., One-step solution deposition of CsPbBr3 based on precursor engineering for efficient all-inorganic perovskite solar cells. J. Mater. Chem. A 2019,7 (39), 22420.
[15] Cheng, Q.; Yin, Z.; Pan, S.; Zhang, G.; Pan, Z.; Yu, X.; Fang, Y.; Rao, H.; Zhong, X., Enhancing Adsorption and Reaction Kinetics of Polysulfides by CoP Coated N-doped Mesoporous Carbon for High-Energy-Density Lithium-Sulfur Batteries. ACS Appl. Mater. Interfaces 2020,12 (39), 43844.
[16] Xie, P.; Zhang, G.; Yang, Z.; Pan, Z.; Fang, Y.; Rao, H.; Zhong, X., Perovskite-Compatible Carbon Electrode Improving the Efficiency and Stability of CsPbI2Br Solar Cells. Solar RRL 2020,4 (9), 2000431.
[17] Yin, Z.; Pan, S.; Cheng, Q.; Zhang, G.; Yu, X.; Pan, Z.; Rao, H.; Zhong, X., Mild-method synthesised rGO–TiO2 as an effective Polysulphide–Barrier for Lithium–Sulphur batteries. J. Alloy. Compd. 2020,836, 155341.
[18] Pan, S.; Yin, Z.; Cheng, Q.; Zhang, G.; Yu, X.; Pan, Z.; Rao, H.; Zhong, X., Bifunctional TiS2/CNT as efficient polysulfide barrier to improve the performance of lithium–sulfur battery. J. Alloy. Compd. 2020,832, 154947.
[19] Song, H.; Pan, Z.; Rao, H.; Zhong, X., TiO2 hierarchical nanowire-P25 particulate composite photoanodes in combination with N-doped mesoporous carbon/Ti counter electrodes for high performance quantum dot-sensitized solar cells. Sol. Energy 2019,191, 459.
2014-2017年
[20] Rao, H.-S.; Li, W.-G.; Chen, B.-X.; Kuang, D.-B.; Su, C.-Y., In Situ Growth of 120 cm2 CH3NH3PbBr3 Perovskite Crystal Film on FTO Glass for Narrowband-Photodetectors. Adv. Mater. 2017,29 (16), 1602639.
[21] Rao, H.-S.; Chen, B.-X.; Wang, X.-D.; Kuang, D.-B.; Su, C.-Y., A micron-scale laminar MAPbBr3 single crystal for an efficient and stable perovskite solar cell. Chem. Commun. 2017,53 (37), 5163.
[22] Rao, H.-S.; Chen, B.-X.; Li, W.-G.; Xu, Y.-F.; Chen, H.-Y.; Kuang, D.-B.; Su, C.-Y., Improving the Extraction of Photogenerated Electrons with SnO2 Nanocolloids for Efficient Planar Perovskite Solar Cells. Adv. Funct. Mater. 2015,25 (46), 7200.
[23] Rao, H.-S.; Wu, W.-Q.; Liu, Y.; Xu, Y.-F.; Chen, B.-X.; Chen, H.-Y.; Kuang, D.-B.; Su, C.-Y., CdS/CdSe co-sensitized vertically aligned anatase TiO2 nanowire arrays for efficient solar cells. Nano Energy 2014,8 (0), 1.
八、主持科研项目
[1] 国家自然科学基金面上项目,2023/01-2026/12,在研,主持;
[2] 广州市基础研究计划基础与应用基础研究项目, 2013/04-2025/03,在研,主持;
[3] 国家自然科学基金青年基金项目,2019/01-2021/12,结题,主持;
[4] 广州市科协青年人才托举工程,2021.03-2023.03,在研,主持
[5] 华南农业大学青年科技人才培育专项基金,2018/01-2019/12,结题,主持;
[6] 华南农业大学高层次引进人才科研启动项目,2017/07-,在研,主持;